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PubMed: On-line coupling of supercritical fluid extraction with enantioselective supercritical fluid chromatography-triple quadrupole mass spectrometry for the determination of chiral pesticides in hemp seeds: A proof-of-principle study

PubMed: On-line coupling of supercritical fluid extraction with enantioselective supercritical fluid chromatography-triple quadrupole mass spectrometry for the determination of chiral pesticides in hemp seeds: A proof-of-principle study

Food Chem. 2021 Oct 20;373(Pt B):131418. doi: 10.1016/j.foodchem.2021.131418. Online ahead of print.

ABSTRACT

The present research can be considered as a proof-of-principle study focused on the determination of chiral pesticides using a supercritical fluid extraction instrument coupled on-line with an enantioselective supercritical fluid chromatography-triple quadrupole mass spectrometry. To the best of Authors’ knowledge, this is the first description of an on-line approach for the extraction and determination of chiral pesticides. Metalaxyl, benalaxyl and dimethenamid were investigated in nine hemp seed samples belonging to four varieties of Cannabis sativa; only in one case a pesticide was found at levels above the method limit of quantification (LoQ), though within the EU maximum residue level value. The figures-of-merit determined were linearity, precision, limit of detection (LoD), and LoQ. Regression coefficients were between 0.9856 and 0.9973, the LoDs were in the 0.04-0.41 μg kg-1 range, the LoQs were in the 0.12-1.38 μg kg-1 range, while coefficients of variation were between 1 and 3% (10 μg kg-1 level).

PMID:34731800 | DOI:10.1016/j.foodchem.2021.131418

#CBD #Hemp https://pubmed.ncbi.nlm.nih.gov/34731800/?utm_source=Chrome&utm_medium=rss&utm_campaign=None&utm_content=1jYCQzi_o_qLYr-oQfnMhShgOXkvGma3vcnBGJtrBhuJMOvEVJ&fc=None&ff=20211104070008&v=2.15.0 November 3, 2021 10:00 am

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